1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone

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Abstract

Enynone 1 undergoes facile 1,6-addition of organocopper reagents to yield allenyl enols 5 which stereoselectively isomerize to Z-dienones 2.

Original languageEnglish (US)
Pages (from-to)5851-5854
Number of pages4
JournalTetrahedron Letters
Volume29
Issue number46
DOIs
StatePublished - 1988
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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