A combined experimental and theoretical study of resonance emission spectra of SO2(C̃ 1B2 )

Brad Parsons, Laurie J. Butler, Daiqian Xie, Hua Guo

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

Experimental and theoretical resonance emission spectra are obtained for a number of vibrational states of SO2(C̃ 1B2). The experimental emission spectra are dominated by (n1ν1, n2ν2, 0) bands, but some weak activity in the anti-symmetric stretch (ν3) is observed. The calculated emission spectra based on an empirical near-equilibrium potential energy surface agree reasonably well with experiment for two lowest states investigated here, but fail to reproduce higher ones. Resonance Raman spectra are also calculated and agree well with an earlier experiment.

Original languageEnglish (US)
Pages (from-to)499-506
Number of pages8
JournalChemical Physics Letters
Volume320
Issue number5-6
DOIs
StatePublished - Apr 14 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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