TY - JOUR
T1 - [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV)
T2 - A New Purely Inorganic d/f-Heterometallic Cationic Material
AU - Poe, Todd N.
AU - White, Frankie D.
AU - Proust, Vanessa
AU - Villa, Eric M.
AU - Polinski, Matthew J.
N1 - Funding Information:
T.N.P. and M.J.P. acknowledge Bloomsburg University of Pennsylvania for financial support. E.M.V. acknowledges Creighton University for financial support. F.D.W. acknowledges Florida State University for financial support. V.P. performed optical measurements and was supported, in part, by the Center for Actinide Science and Technology, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under Award DESC0016568.
PY - 2018/5/7
Y1 - 2018/5/7
N2 - Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O52- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.
AB - Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O52- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.
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U2 - 10.1021/acs.inorgchem.8b00504
DO - 10.1021/acs.inorgchem.8b00504
M3 - Article
C2 - 29658710
AN - SCOPUS:85046622433
VL - 57
SP - 4816
EP - 4819
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 9
ER -