Abstract
Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O5 2- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4816-4819 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry |
| Volume | 57 |
| Issue number | 9 |
| DOIs | |
| State | Published - May 7 2018 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Cite this
[Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV) : A New Purely Inorganic d/f-Heterometallic Cationic Material. / Poe, Todd N.; White, Frankie D.; Proust, Vanessa; Villa, Eric; Polinski, Matthew J.
In: Inorganic Chemistry, Vol. 57, No. 9, 07.05.2018, p. 4816-4819.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV)
T2 - A New Purely Inorganic d/f-Heterometallic Cationic Material
AU - Poe, Todd N.
AU - White, Frankie D.
AU - Proust, Vanessa
AU - Villa, Eric
AU - Polinski, Matthew J.
PY - 2018/5/7
Y1 - 2018/5/7
N2 - Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O5 2- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.
AB - Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O5 2- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.
UR - http://www.scopus.com/inward/record.url?scp=85046622433&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85046622433&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.8b00504
DO - 10.1021/acs.inorgchem.8b00504
M3 - Article
VL - 57
SP - 4816
EP - 4819
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 9
ER -