Abstract
Allenyl enolates generated from 1,6 additions of organocopper reagents to 3-ethynyl-2-cycloalkenones act as ambident α,γ-nucleophiles. The γ:α ratio of products is a function of carbon hybridization, steric environment, and cycloalkenone ring size; typically, γ-products predominate.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 185-188 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 33 |
| Issue number | 2 |
| DOIs | |
| State | Published - 1992 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Lee, S. H., Shih, M. J., & Hulce, M. (1992). Ambiphilic allenyl enolates: reactions with electrophiles. Tetrahedron Letters, 33(2), 185-188. https://doi.org/10.1016/0040-4039(92)88045-7