Anion photoelectron spectroscopy of C5 H-

Sean M. Sheehan; Bradley F. Parsons; Terry A. Yen; Michael R. Furlanetto; Daniel M. Neumark

doi:10.1063/1.2912056

Anion photoelectron spectroscopy of C₅ H-

Sean M. Sheehan, Bradley F. Parsons, Terry A. Yen, Michael R. Furlanetto, Daniel M. Neumark

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Anion photoelectron spectroscopy is performed on the C5 H- species. Analogous to C3 H- and C3 D-, photodetachment transitions are observed from multiple, energetically close-lying isomers of the anion. A linear and a cyclic structure are found to have electron binding energies of 2.421±0.019 eV and 2.857±0.028 eV, respectively. A cyclic excited state is also found to be 1.136 eV above the linear Π2 C5 H ground state. Based on our assignments of the observed transitions and previous calculations on the energetics of neutral C5 H isomers, the cyclic A11 anion state is found to lie 0.163 eV below the A3 linear anion.

Original language	English (US)
Article number	174301
Journal	Journal of Chemical Physics
Volume	128
Issue number	17
DOIs	https://doi.org/10.1063/1.2912056
State	Published - 2008

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.2912056

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@article{e99c88ba981c4aa6ace57f193f72258d,

title = "Anion photoelectron spectroscopy of C5 H-",

abstract = "Anion photoelectron spectroscopy is performed on the C5 H- species. Analogous to C3 H- and C3 D-, photodetachment transitions are observed from multiple, energetically close-lying isomers of the anion. A linear and a cyclic structure are found to have electron binding energies of 2.421±0.019 eV and 2.857±0.028 eV, respectively. A cyclic excited state is also found to be 1.136 eV above the linear Π2 C5 H ground state. Based on our assignments of the observed transitions and previous calculations on the energetics of neutral C5 H isomers, the cyclic A11 anion state is found to lie 0.163 eV below the A3 linear anion.",

author = "Sheehan, {Sean M.} and Parsons, {Bradley F.} and Yen, {Terry A.} and Furlanetto, {Michael R.} and Neumark, {Daniel M.}",

note = "Funding Information: This research is supported by the National Science Foundation under Grant No. DMR-0139064.",

year = "2008",

doi = "10.1063/1.2912056",

language = "English (US)",

volume = "128",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "17",

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TY - JOUR

T1 - Anion photoelectron spectroscopy of C5 H-

AU - Sheehan, Sean M.

AU - Parsons, Bradley F.

AU - Yen, Terry A.

AU - Furlanetto, Michael R.

AU - Neumark, Daniel M.

N1 - Funding Information: This research is supported by the National Science Foundation under Grant No. DMR-0139064.

PY - 2008

Y1 - 2008

N2 - Anion photoelectron spectroscopy is performed on the C5 H- species. Analogous to C3 H- and C3 D-, photodetachment transitions are observed from multiple, energetically close-lying isomers of the anion. A linear and a cyclic structure are found to have electron binding energies of 2.421±0.019 eV and 2.857±0.028 eV, respectively. A cyclic excited state is also found to be 1.136 eV above the linear Π2 C5 H ground state. Based on our assignments of the observed transitions and previous calculations on the energetics of neutral C5 H isomers, the cyclic A11 anion state is found to lie 0.163 eV below the A3 linear anion.

AB - Anion photoelectron spectroscopy is performed on the C5 H- species. Analogous to C3 H- and C3 D-, photodetachment transitions are observed from multiple, energetically close-lying isomers of the anion. A linear and a cyclic structure are found to have electron binding energies of 2.421±0.019 eV and 2.857±0.028 eV, respectively. A cyclic excited state is also found to be 1.136 eV above the linear Π2 C5 H ground state. Based on our assignments of the observed transitions and previous calculations on the energetics of neutral C5 H isomers, the cyclic A11 anion state is found to lie 0.163 eV below the A3 linear anion.

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DO - 10.1063/1.2912056

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 17

M1 - 174301

ER -

Anion photoelectron spectroscopy of C₅ H-

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