Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water

Eric Villa, C. André Ohlin, William H. Casey

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Borate: guilty and charged! The borate ion, and possibly carbonate, enhances rates of steady oxygen-isotope exchanges at some, but not all, structural sites in polyoxometalate ions. Addition of an oxygen atom to an incoming neutral boric acid molecule (blue = boron) from a bridging oxygen atom on a decametalate ion is shown here. (Figure Presented)

Original languageEnglish
Pages (from-to)8631-8634
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number29
DOIs
StatePublished - Aug 2 2010
Externally publishedYes

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Oxygen Isotopes
Borates
Isotopes
Ion exchange
Ions
Oxygen
Water
Atoms
Boric acid
Boron
Carbonates
Molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water. / Villa, Eric; André Ohlin, C.; Casey, William H.

In: Chemistry - A European Journal, Vol. 16, No. 29, 02.08.2010, p. 8631-8634.

Research output: Contribution to journalArticle

Villa, Eric ; André Ohlin, C. ; Casey, William H. / Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water. In: Chemistry - A European Journal. 2010 ; Vol. 16, No. 29. pp. 8631-8634.
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