Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water

Eric M. Villa; C. André Ohlin; William H. Casey

doi:10.1002/chem.201000946

Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water

Eric M. Villa, C. André Ohlin, William H. Casey

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Borate: guilty and charged! The borate ion, and possibly carbonate, enhances rates of steady oxygen-isotope exchanges at some, but not all, structural sites in polyoxometalate ions. Addition of an oxygen atom to an incoming neutral boric acid molecule (blue = boron) from a bridging oxygen atom on a decametalate ion is shown here. (Figure Presented)

Original language	English (US)
Pages (from-to)	8631-8634
Number of pages	4
Journal	Chemistry - A European Journal
Volume	16
Issue number	29
DOIs	https://doi.org/10.1002/chem.201000946
State	Published - Aug 2 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/chem.201000946

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title = "Borate accelerates rates of steady oxygen-isotope exchange for polyoxoniobate ions in water",

abstract = "Borate: guilty and charged! The borate ion, and possibly carbonate, enhances rates of steady oxygen-isotope exchanges at some, but not all, structural sites in polyoxometalate ions. Addition of an oxygen atom to an incoming neutral boric acid molecule (blue = boron) from a bridging oxygen atom on a decametalate ion is shown here. (Figure Presented)",

author = "Villa, {Eric M.} and {Andr{\'e} Ohlin}, C. and Casey, {William H.}",

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AU - Casey, William H.

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Y1 - 2010/8/2

N2 - Borate: guilty and charged! The borate ion, and possibly carbonate, enhances rates of steady oxygen-isotope exchanges at some, but not all, structural sites in polyoxometalate ions. Addition of an oxygen atom to an incoming neutral boric acid molecule (blue = boron) from a bridging oxygen atom on a decametalate ion is shown here. (Figure Presented)

AB - Borate: guilty and charged! The borate ion, and possibly carbonate, enhances rates of steady oxygen-isotope exchanges at some, but not all, structural sites in polyoxometalate ions. Addition of an oxygen atom to an incoming neutral boric acid molecule (blue = boron) from a bridging oxygen atom on a decametalate ion is shown here. (Figure Presented)

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