Abstract
Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 10083-10085 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 51 |
| Issue number | 19 |
| DOIs | |
| State | Published - Oct 1 2012 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Lin, J., Diwu, J., Cross, J. N., Villa, E. M., & Albrecht-Schmitt, T. E. (2012). Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks. Inorganic Chemistry, 51(19), 10083-10085. https://doi.org/10.1021/ic301628q