Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks

Jian Lin; Juan Diwu; Justin N. Cross; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301628q

Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks

Jian Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Two isotypic cerium tellurite halides with the formulas [Ce ₂Te ₇O ₁₇]Cl ₂ and [Ce ₂Te ₇O ₁₇]Br ₂ have been synthesized hydrothermally via the reactions of CeCl ₃ and CeBr ₃ with TeO ₂. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te ₇O ₁₇ ^6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce ^IV.

Original language	English (US)
Pages (from-to)	10083-10085
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	19
DOIs	https://doi.org/10.1021/ic301628q
State	Published - Oct 1 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic301628q

Cite this

@article{1daef2ed21d8416cba4a5481ebc9fdda,

title = "Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks",

abstract = "Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.",

author = "Jian Lin and Juan Diwu and Cross, {Justin N.} and Villa, {Eric M.} and Albrecht-Schmitt, {Thomas E.}",

year = "2012",

month = oct,

day = "1",

doi = "10.1021/ic301628q",

language = "English (US)",

volume = "51",

pages = "10083--10085",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)

T2 - The first cerium-containing cationic frameworks

AU - Lin, Jian

AU - Diwu, Juan

AU - Cross, Justin N.

AU - Villa, Eric M.

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/10/1

Y1 - 2012/10/1

N2 - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

AB - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

UR - http://www.scopus.com/inward/record.url?scp=84868129074&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84868129074&partnerID=8YFLogxK

U2 - 10.1021/ic301628q

DO - 10.1021/ic301628q

M3 - Article

AN - SCOPUS:84868129074

VL - 51

SP - 10083

EP - 10085

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 19

ER -

Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this