Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)

The first cerium-containing cationic frameworks

Jian Lin, Juan Diwu, Justin N. Cross, Eric Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

Original languageEnglish
Pages (from-to)10083-10085
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number19
DOIs
StatePublished - Oct 1 2012
Externally publishedYes

Fingerprint

Cerium
cerium
Dimers
halides
dimers
tellurous acid

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -) : The first cerium-containing cationic frameworks. / Lin, Jian; Diwu, Juan; Cross, Justin N.; Villa, Eric; Albrecht-Schmitt, Thomas E.

In: Inorganic Chemistry, Vol. 51, No. 19, 01.10.2012, p. 10083-10085.

Research output: Contribution to journalArticle

Lin, Jian ; Diwu, Juan ; Cross, Justin N. ; Villa, Eric ; Albrecht-Schmitt, Thomas E. / Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -) : The first cerium-containing cationic frameworks. In: Inorganic Chemistry. 2012 ; Vol. 51, No. 19. pp. 10083-10085.
@article{1daef2ed21d8416cba4a5481ebc9fdda,
title = "Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks",
abstract = "Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.",
author = "Jian Lin and Juan Diwu and Cross, {Justin N.} and Eric Villa and Albrecht-Schmitt, {Thomas E.}",
year = "2012",
month = "10",
day = "1",
doi = "10.1021/ic301628q",
language = "English",
volume = "51",
pages = "10083--10085",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "19",

}

TY - JOUR

T1 - Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)

T2 - The first cerium-containing cationic frameworks

AU - Lin, Jian

AU - Diwu, Juan

AU - Cross, Justin N.

AU - Villa, Eric

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/10/1

Y1 - 2012/10/1

N2 - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

AB - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

UR - http://www.scopus.com/inward/record.url?scp=84868129074&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84868129074&partnerID=8YFLogxK

U2 - 10.1021/ic301628q

DO - 10.1021/ic301628q

M3 - Article

VL - 51

SP - 10083

EP - 10085

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 19

ER -