Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)

The first cerium-containing cationic frameworks

Jian Lin, Juan Diwu, Justin N. Cross, Eric Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article

21 Citations (Scopus)

Abstract

Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

Original languageEnglish
Pages (from-to)10083-10085
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number19
DOIs
StatePublished - Oct 1 2012
Externally publishedYes

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Cerium
cerium
Dimers
halides
dimers
tellurous acid

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -) : The first cerium-containing cationic frameworks. / Lin, Jian; Diwu, Juan; Cross, Justin N.; Villa, Eric; Albrecht-Schmitt, Thomas E.

In: Inorganic Chemistry, Vol. 51, No. 19, 01.10.2012, p. 10083-10085.

Research output: Contribution to journal › Article

Lin, J, Diwu, J, Cross, JN, Villa, E & Albrecht-Schmitt, TE 2012, 'Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks', Inorganic Chemistry, vol. 51, no. 19, pp. 10083-10085. https://doi.org/10.1021/ic301628q
Lin J, Diwu J, Cross JN, Villa E, Albrecht-Schmitt TE. Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks. Inorganic Chemistry. 2012 Oct 1;51(19):10083-10085. https://doi.org/10.1021/ic301628q
Lin, Jian ; Diwu, Juan ; Cross, Justin N. ; Villa, Eric ; Albrecht-Schmitt, Thomas E. / Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -) : The first cerium-containing cationic frameworks. In: Inorganic Chemistry. 2012 ; Vol. 51, No. 19. pp. 10083-10085.
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