Abstract
Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.
| Original language | English |
|---|---|
| Pages (from-to) | 10083-10085 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 51 |
| Issue number | 19 |
| DOIs | |
| State | Published - Oct 1 2012 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Inorganic Chemistry
- Physical and Theoretical Chemistry
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Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -) : The first cerium-containing cationic frameworks. / Lin, Jian; Diwu, Juan; Cross, Justin N.; Villa, Eric; Albrecht-Schmitt, Thomas E.
In: Inorganic Chemistry, Vol. 51, No. 19, 01.10.2012, p. 10083-10085.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)
T2 - The first cerium-containing cationic frameworks
AU - Lin, Jian
AU - Diwu, Juan
AU - Cross, Justin N.
AU - Villa, Eric
AU - Albrecht-Schmitt, Thomas E.
PY - 2012/10/1
Y1 - 2012/10/1
N2 - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.
AB - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.
UR - http://www.scopus.com/inward/record.url?scp=84868129074&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84868129074&partnerID=8YFLogxK
U2 - 10.1021/ic301628q
DO - 10.1021/ic301628q
M3 - Article
AN - SCOPUS:84868129074
VL - 51
SP - 10083
EP - 10085
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 19
ER -