Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks

Jian Lin; Juan Diwu; Justin N. Cross; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301628q

Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks

Jian Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Two isotypic cerium tellurite halides with the formulas [Ce ₂Te ₇O ₁₇]Cl ₂ and [Ce ₂Te ₇O ₁₇]Br ₂ have been synthesized hydrothermally via the reactions of CeCl ₃ and CeBr ₃ with TeO ₂. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te ₇O ₁₇ ^6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce ^IV.

Original language	English (US)
Pages (from-to)	10083-10085
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	19
DOIs	https://doi.org/10.1021/ic301628q
State	Published - Oct 1 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic301628q

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title = "Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks",

abstract = "Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.",

author = "Jian Lin and Juan Diwu and Cross, {Justin N.} and Villa, {Eric M.} and Albrecht-Schmitt, {Thomas E.}",

year = "2012",

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doi = "10.1021/ic301628q",

language = "English (US)",

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T1 - Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -)

T2 - The first cerium-containing cationic frameworks

AU - Lin, Jian

AU - Diwu, Juan

AU - Cross, Justin N.

AU - Villa, Eric M.

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/10/1

Y1 - 2012/10/1

N2 - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

AB - Two isotypic cerium tellurite halides with the formulas [Ce 2Te 7O 17]Cl 2 and [Ce 2Te 7O 17]Br 2 have been synthesized hydrothermally via the reactions of CeCl 3 and CeBr 3 with TeO 2. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te 7O 17 6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce IV.

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Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks

Abstract

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