Cerium(IV) tellurite halides [Ce 2Te 7O 17]X 2 (X = Cl - or Br -): The first cerium-containing cationic frameworks

Jian Lin; Juan Diwu; Justin N. Cross; Eric Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301628q

Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks

Jian Lin, Juan Diwu, Justin N. Cross, Eric Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article

24 Scopus citations

Abstract

Two isotypic cerium tellurite halides with the formulas [Ce ₂Te ₇O ₁₇]Cl ₂ and [Ce ₂Te ₇O ₁₇]Br ₂ have been synthesized hydrothermally via the reactions of CeCl ₃ and CeBr ₃ with TeO ₂. The structures of these compounds feature a cationic inorganic framework. The CeIV dimers are bound by a novel 3D Te ₇O ₁₇ ^6- building unit, forming an unusual hexagonal-bipyramidal environment around Ce ^IV.

Original language	English
Pages (from-to)	10083-10085
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	19
DOIs	https://doi.org/10.1021/ic301628q
Publication status	Published - Oct 1 2012
Externally published	Yes

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All Science Journal Classification (ASJC) codes

Inorganic Chemistry
Physical and Theoretical Chemistry

Cite this

Lin, J., Diwu, J., Cross, J. N., Villa, E., & Albrecht-Schmitt, T. E. (2012). Cerium(IV) tellurite halides [Ce ₂Te ₇O ₁₇]X ₂ (X = Cl ^- or Br ^-): The first cerium-containing cationic frameworks. Inorganic Chemistry, 51(19), 10083-10085. https://doi.org/10.1021/ic301628q

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10.1021/ic301628q