TY - JOUR
T1 - Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride
AU - Trischler, Aaron
AU - Oshin, Kayode
AU - Pintauer, Tomislav
N1 - Funding Information:
KO would like to thank Dr. Matthias Zeller for crystallographic support and Youngstown State University for instrument support. The X-ray diffractometer was funded by NSF grant No. 1337296, and Project SEED student (AT) was funded by the American Chemical Society. Research funding from The Weber Foundation, Cambridge Isotope Laboratories Inc., and Thermo-Fisher Scientific are also gratefully acknowledged.
PY - 2015/9/1
Y1 - 2015/9/1
N2 - In the title molecular salt, C12H14N3+·NH4+·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.
AB - In the title molecular salt, C12H14N3+·NH4+·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.
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U2 - 10.1107/S2056989015015753
DO - 10.1107/S2056989015015753
M3 - Article
AN - SCOPUS:84957541840
VL - 71
SP - o692-o693
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
ER -