Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler; Kayode Oshin; Tomislav Pintauer

doi:10.1107/S2056989015015753

Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler, Kayode Oshin, Tomislav Pintauer

Research output: Contribution to journal › Article › peer-review

Abstract

In the title molecular salt, C₁₂H₁₄N₃⁺·NH₄⁺·2Cl^-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

Original language	English (US)
Pages (from-to)	o692-o693
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	71
DOIs	https://doi.org/10.1107/S2056989015015753
State	Published - Sep 1 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S2056989015015753

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title = "Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride",

abstract = "In the title molecular salt, C12H14N3+·NH4+·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.",

author = "Aaron Trischler and Kayode Oshin and Tomislav Pintauer",

note = "Funding Information: KO would like to thank Dr. Matthias Zeller for crystallographic support and Youngstown State University for instrument support. The X-ray diffractometer was funded by NSF grant No. 1337296, and Project SEED student (AT) was funded by the American Chemical Society. Research funding from The Weber Foundation, Cambridge Isotope Laboratories Inc., and Thermo-Fisher Scientific are also gratefully acknowledged.",

year = "2015",

month = sep,

day = "1",

doi = "10.1107/S2056989015015753",

language = "English (US)",

volume = "71",

pages = "o692--o693",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

AU - Trischler, Aaron

AU - Oshin, Kayode

AU - Pintauer, Tomislav

N1 - Funding Information: KO would like to thank Dr. Matthias Zeller for crystallographic support and Youngstown State University for instrument support. The X-ray diffractometer was funded by NSF grant No. 1337296, and Project SEED student (AT) was funded by the American Chemical Society. Research funding from The Weber Foundation, Cambridge Isotope Laboratories Inc., and Thermo-Fisher Scientific are also gratefully acknowledged.

PY - 2015/9/1

Y1 - 2015/9/1

N2 - In the title molecular salt, C12H14N3+·NH4+·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

AB - In the title molecular salt, C12H14N3+·NH4+·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

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