Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler; Kayode Oshin; Tomislav Pintauer

doi:10.1107/S2056989015015753

Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler, Kayode Oshin, Tomislav Pintauer

Research output: Contribution to journal › Article

Abstract

In the title molecular salt, C₁₂H₁₄N₃ ⁺·NH₄ ⁺·2Cl^-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

Original language	English (US)
Pages (from-to)	o692-o693
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	71
DOIs	https://doi.org/10.1107/S2056989015015753
Publication status	Published - Sep 1 2015
Externally published	Yes

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All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Materials Science(all)
Chemistry(all)

Cite this

Trischler, A., Oshin, K., & Pintauer, T. (2015). Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. Acta Crystallographica Section E: Crystallographic Communications, 71, o692-o693. https://doi.org/10.1107/S2056989015015753

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10.1107/S2056989015015753