Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler; Kayode Oshin; Tomislav Pintauer

doi:10.1107/S2056989015015753

Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler, Kayode Oshin, Tomislav Pintauer

Research output: Contribution to journal › Article

Abstract

In the title molecular salt, C₁₂H₁₄N₃ ⁺·NH₄ ⁺·2Cl^-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

Original language	English (US)
Pages (from-to)	o692-o693
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	71
DOIs	https://doi.org/10.1107/S2056989015015753
State	Published - Sep 1 2015
Externally published	Yes

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dichlorides

Ammonium Compounds

Hydrogen bonds

Crystal structure

hydrogen bonds

crystal structure

Dihedral angle

Pyridine

Amines

dihedral angle

Cations

pyridines

amines

Salts

Positive ions

salts

cations

Atoms

Crystals

rings

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Materials Science(all)
Chemistry(all)

Cite this

Trischler, A., Oshin, K., & Pintauer, T. (2015). Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. Acta Crystallographica Section E: Crystallographic Communications, 71, o692-o693. https://doi.org/10.1107/S2056989015015753

Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. / Trischler, Aaron; Oshin, Kayode; Pintauer, Tomislav.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 71, 01.09.2015, p. o692-o693.

Research output: Contribution to journal › Article

Trischler, A, Oshin, K & Pintauer, T 2015, 'Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride', Acta Crystallographica Section E: Crystallographic Communications, vol. 71, pp. o692-o693. https://doi.org/10.1107/S2056989015015753

Trischler A, Oshin K, Pintauer T. Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. Acta Crystallographica Section E: Crystallographic Communications. 2015 Sep 1;71:o692-o693. https://doi.org/10.1107/S2056989015015753

Trischler, Aaron ; Oshin, Kayode ; Pintauer, Tomislav. / Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. In: Acta Crystallographica Section E: Crystallographic Communications. 2015 ; Vol. 71. pp. o692-o693.

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10.1107/S2056989015015753