Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride

Aaron Trischler, Kayode Oshin, Tomislav Pintauer

Research output: Contribution to journalArticle

Abstract

In the title molecular salt, C12H14N3 +·NH4 +·2Cl-, the central, secondary-amine, N atom is protonated. The bis[(pyridin-2- yl)methyl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional network.

Original languageEnglish (US)
Pages (from-to)o692-o693
JournalActa Crystallographica Section E: Crystallographic Communications
Volume71
DOIs
StatePublished - Sep 1 2015
Externally publishedYes

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dichlorides
Ammonium Compounds
Hydrogen bonds
Crystal structure
hydrogen bonds
crystal structure
Dihedral angle
Pyridine
Amines
dihedral angle
Cations
pyridines
amines
Salts
Positive ions
salts
cations
Atoms
Crystals
rings

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of ammonium bis[(pyridin-2-yl)methyl]ammonium dichloride. / Trischler, Aaron; Oshin, Kayode; Pintauer, Tomislav.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 71, 01.09.2015, p. o692-o693.

Research output: Contribution to journalArticle

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