Abstract
The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 309-311 |
| Number of pages | 3 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 71 |
| Issue number | 3 |
| DOIs | |
| State | Published - Jan 1 2015 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. / Bussey, Katherine A.; Connell, Jennifer R.; McGlone, Annie R.; Mraz, Margaret E.; Oshin, Kayode; Pintauer, Tomislav; Oliver, Allen G.; Parkin, S.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 3, 01.01.2015, p. 309-311.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate
AU - Bussey, Katherine A.
AU - Connell, Jennifer R.
AU - McGlone, Annie R.
AU - Mraz, Margaret E.
AU - Oshin, Kayode
AU - Pintauer, Tomislav
AU - Oliver, Allen G.
AU - Parkin, S.
PY - 2015/1/1
Y1 - 2015/1/1
N2 - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.
AB - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.
UR - http://www.scopus.com/inward/record.url?scp=84928164489&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84928164489&partnerID=8YFLogxK
U2 - 10.1107/S2056989015003448
DO - 10.1107/S2056989015003448
M3 - Article
VL - 71
SP - 309
EP - 311
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 3
ER -