Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey; Jennifer R. Connell; Annie R. McGlone; Margaret E. Mraz; Kayode D. Oshin; Tomislav Pintauer; Allen G. Oliver; S. Parkin

doi:10.1107/S2056989015003448

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey, Jennifer R. Connell, Annie R. McGlone, Margaret E. Mraz, Kayode D. Oshin, Tomislav Pintauer, Allen G. Oliver, S. Parkin

Department of Chemistry

Research output: Contribution to journal › Article

Abstract

The five-coordinate Cu^II atom in the title complex [CuCl₂(C₁₆H₁₉N₃)]·-0.5C₄H₁₀O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

Original language	English (US)
Pages (from-to)	309-311
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
DOIs	https://doi.org/10.1107/S2056989015003448
State	Published - Mar 1 2015

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Bussey, K. A., Connell, J. R., McGlone, A. R., Mraz, M. E., Oshin, K. D., Pintauer, T., Oliver, A. G., & Parkin, S. (2015). Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 71(3), 309-311. https://doi.org/10.1107/S2056989015003448

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. / Bussey, Katherine A.; Connell, Jennifer R.; McGlone, Annie R.; Mraz, Margaret E.; Oshin, Kayode D.; Pintauer, Tomislav; Oliver, Allen G.; Parkin, S.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 3, 01.03.2015, p. 309-311.

Research output: Contribution to journal › Article

Bussey, Katherine A. ; Connell, Jennifer R. ; McGlone, Annie R. ; Mraz, Margaret E. ; Oshin, Kayode D. ; Pintauer, Tomislav ; Oliver, Allen G. ; Parkin, S. / Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 3. pp. 309-311.

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abstract = "The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) {\AA} longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.",

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T1 - Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

AU - Bussey, Katherine A.

AU - Connell, Jennifer R.

AU - McGlone, Annie R.

AU - Mraz, Margaret E.

AU - Oshin, Kayode D.

AU - Pintauer, Tomislav

AU - Oliver, Allen G.

AU - Parkin, S.

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N2 - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

AB - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

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10.1107/S2056989015003448