Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey; Jennifer R. Connell; Annie R. McGlone; Margaret E. Mraz; Kayode D. Oshin; Tomislav Pintauer; Allen G. Oliver; S. Parkin

doi:10.1107/S2056989015003448

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey, Jennifer R. Connell, Annie R. McGlone, Margaret E. Mraz, Kayode D. Oshin, Tomislav Pintauer, Allen G. Oliver, S. Parkin

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The five-coordinate Cu^II atom in the title complex [CuCl₂(C₁₆H₁₉N₃)]·-0.5C₄H₁₀O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

Original language	English (US)
Pages (from-to)	309-311
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
DOIs	https://doi.org/10.1107/S2056989015003448
State	Published - Mar 1 2015

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Bussey, K. A., Connell, J. R., McGlone, A. R., Mraz, M. E., Oshin, K. D., Pintauer, T., Oliver, A. G., & Parkin, S. (2015). Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 71(3), 309-311. https://doi.org/10.1107/S2056989015003448

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. / Bussey, Katherine A.; Connell, Jennifer R.; McGlone, Annie R.; Mraz, Margaret E.; Oshin, Kayode D.; Pintauer, Tomislav; Oliver, Allen G.; Parkin, S.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 3, 01.03.2015, p. 309-311.

Research output: Contribution to journal › Article › peer-review

Bussey, Katherine A. ; Connell, Jennifer R. ; McGlone, Annie R. ; Mraz, Margaret E. ; Oshin, Kayode D. ; Pintauer, Tomislav ; Oliver, Allen G. ; Parkin, S. / Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ³N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 3. pp. 309-311.

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abstract = "The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) {\AA} longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.",

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AU - Bussey, Katherine A.

AU - Connell, Jennifer R.

AU - McGlone, Annie R.

AU - Mraz, Margaret E.

AU - Oshin, Kayode D.

AU - Pintauer, Tomislav

AU - Oliver, Allen G.

AU - Parkin, S.

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AB - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

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