Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate

Katherine A. Bussey, Jennifer R. Connell, Annie R. McGlone, Margaret E. Mraz, Kayode Oshin, Tomislav Pintauer, Allen G. Oliver, S. Parkin

Research output: Contribution to journalArticle

Abstract

The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

Original languageEnglish (US)
Pages (from-to)309-311
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number3
DOIs
StatePublished - Jan 1 2015
Externally publishedYes

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diethyl ether
Ether
Amines
Copper
Ethers
amines
Crystal structure
copper
Atoms
crystal structure
atoms
Addition reactions
Molecules
Pyridine
molecules
voids
pyridines
Nitrogen
Ligands
nitrogen

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. / Bussey, Katherine A.; Connell, Jennifer R.; McGlone, Annie R.; Mraz, Margaret E.; Oshin, Kayode; Pintauer, Tomislav; Oliver, Allen G.; Parkin, S.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 3, 01.01.2015, p. 309-311.

Research output: Contribution to journalArticle

Bussey, Katherine A. ; Connell, Jennifer R. ; McGlone, Annie R. ; Mraz, Margaret E. ; Oshin, Kayode ; Pintauer, Tomislav ; Oliver, Allen G. ; Parkin, S. / Crystal structure of {(but-3-en-1-yl) bis[(pyridin-2-yl) methyl]amine-κ3N,N′,N″}dichlorido-copper(II) diethyl ether hemisolvate. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 3. pp. 309-311.
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abstract = "The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) {\AA} longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.",
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AU - Bussey, Katherine A.

AU - Connell, Jennifer R.

AU - McGlone, Annie R.

AU - Mraz, Margaret E.

AU - Oshin, Kayode

AU - Pintauer, Tomislav

AU - Oliver, Allen G.

AU - Parkin, S.

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AB - The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·-0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu - Cl distance is 0.2626 (6) Å longer than the basal Cu - Cl distance. Weak C - H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

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