Crystal structure of Li3Ga(BO3)2

Robert W. Smith; Darien Holman; Eric M. Villa

doi:10.1107/S205698901700295X

Crystal structure of Li₃Ga(BO₃)₂

Robert W. Smith, Darien Holman, Eric M. Villa

Department of Chemistry

Research output: Contribution to journal › Article

2 Scopus citations

Abstract

The crystal structure of trilithium gallium bis-(orthoborate), Li₃Ga(BO₃)₂, is isotypic with Li₃Al(BO₃)₂ in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra-hedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga₂(BO₃)₄]^6- extend along the a axis. The Li atoms inter-leave these chains in tetra-hedral inter-stices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972). Zh. Strukt. Khim. 13, 943-946.].

Original language	English (US)
Pages (from-to)	456-458
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	73
DOIs	https://doi.org/10.1107/S205698901700295X
State	Published - 2017

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Smith, R. W., Holman, D., & Villa, E. M. (2017). Crystal structure of Li₃Ga(BO₃)₂. Acta Crystallographica Section E: Crystallographic Communications, 73, 456-458. https://doi.org/10.1107/S205698901700295X

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abstract = "The crystal structure of trilithium gallium bis-(orthoborate), Li3Ga(BO3)2, is isotypic with Li3Al(BO3)2 in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra-hedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga2(BO3)4]6- extend along the a axis. The Li atoms inter-leave these chains in tetra-hedral inter-stices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972). Zh. Strukt. Khim. 13, 943-946.].",

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AB - The crystal structure of trilithium gallium bis-(orthoborate), Li3Ga(BO3)2, is isotypic with Li3Al(BO3)2 in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra-hedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga2(BO3)4]6- extend along the a axis. The Li atoms inter-leave these chains in tetra-hedral inter-stices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972). Zh. Strukt. Khim. 13, 943-946.].

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