Abstract
The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 949-953 |
| Number of pages | 5 |
| Journal | Acta Crystallographica Section E: Crystallographic Communications |
| Volume | 73 |
| DOIs | |
| State | Published - Jan 1 2017 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Crystal structure of {(R)-N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4 N,N′,N″,N″}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate Skokan Shayna R. / Skokan, Shayna R.; Reeson, Monica M.; Oshin, Kayode; Vinokur, Anastasiya I.; Desper, John A.; Levy, Christopher J.
In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 73, 01.01.2017, p. 949-953.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Crystal structure of {(R)-N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4 N,N′,N″,N″}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate Skokan Shayna R.
AU - Skokan, Shayna R.
AU - Reeson, Monica M.
AU - Oshin, Kayode
AU - Vinokur, Anastasiya I.
AU - Desper, John A.
AU - Levy, Christopher J.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.
AB - The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.
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U2 - 10.1107/S2056989017008027
DO - 10.1107/S2056989017008027
M3 - Article
AN - SCOPUS:85023208164
VL - 73
SP - 949
EP - 953
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
ER -