Crystal structure of {(R)-N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4 N,N′,N″,N″}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate Skokan Shayna R.

Shayna R. Skokan, Monica M. Reeson, Kayode Oshin, Anastasiya I. Vinokur, John A. Desper, Christopher J. Levy

Research output: Contribution to journalArticle

Abstract

The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.

Original languageEnglish (US)
Pages (from-to)949-953
Number of pages5
JournalActa Crystallographica Section E: Crystallographic Communications
Volume73
DOIs
StatePublished - Jan 1 2017

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Diamines
Methylene Chloride
quinoline
Dichloromethane
diamines
Imines
Zinc
zinc
Crystal structure
Ligands
imines
Atoms
ligands
crystal structure
Bond length
Molecules
atoms
molecules
Chemical bonds
Torsional stress

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "Crystal structure of {(R)-N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4 N,N′,N″,N″}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate Skokan Shayna R.",
abstract = "The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.",
author = "Skokan, {Shayna R.} and Reeson, {Monica M.} and Kayode Oshin and Vinokur, {Anastasiya I.} and Desper, {John A.} and Levy, {Christopher J.}",
year = "2017",
month = "1",
day = "1",
doi = "10.1107/S2056989017008027",
language = "English (US)",
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journal = "Acta Crystallographica Section E: Crystallographic Communications",
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publisher = "International Union of Crystallography",

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T1 - Crystal structure of {(R)-N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4 N,N′,N″,N″}(trifluoromethanesulfonato-κO)zinc(II)} trifluoromethanesulfonate dichloromethane 1.5-solvate Skokan Shayna R.

AU - Skokan, Shayna R.

AU - Reeson, Monica M.

AU - Oshin, Kayode

AU - Vinokur, Anastasiya I.

AU - Desper, John A.

AU - Levy, Christopher J.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.

AB - The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N 2-[(benzo[h]quinolin-2-yl)methyl]-N 2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π-π and/or σ-π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.

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JF - Acta Crystallographica Section E: Crystallographic Communications

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