Abstract
In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuII ion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal-bipyramidal geometry.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 801-804 |
| Number of pages | 4 |
| Journal | Acta Crystallographica Section E: Crystallographic Communications |
| Volume | 72 |
| DOIs | |
| State | Published - Jun 1 2016 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Crystal structure of [tris(pyridin-2-ylmethyl)amine-κ4 N]copper(II) bromide. / Bridgman, Emma C.; Doherty, Megan M.; Ellis, Kaleigh A.; Homer, Elizabeth A.; Lashbrook, Taylor N.; Mraz, Margaret E.; Pernesky, Gina C.; Vreeke, Emma M.; Oshin, Kayode; Oliver, Allen G.
In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 72, 01.06.2016, p. 801-804.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Crystal structure of [tris(pyridin-2-ylmethyl)amine-κ4 N]copper(II) bromide
AU - Bridgman, Emma C.
AU - Doherty, Megan M.
AU - Ellis, Kaleigh A.
AU - Homer, Elizabeth A.
AU - Lashbrook, Taylor N.
AU - Mraz, Margaret E.
AU - Pernesky, Gina C.
AU - Vreeke, Emma M.
AU - Oshin, Kayode
AU - Oliver, Allen G.
PY - 2016/6/1
Y1 - 2016/6/1
N2 - In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuII ion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal-bipyramidal geometry.
AB - In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuII ion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal-bipyramidal geometry.
UR - http://www.scopus.com/inward/record.url?scp=84973333088&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84973333088&partnerID=8YFLogxK
U2 - 10.1107/S2056989016007568
DO - 10.1107/S2056989016007568
M3 - Article
VL - 72
SP - 801
EP - 804
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
ER -