Abstract
In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuII ion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal-bipyramidal geometry.
Original language | English (US) |
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Pages (from-to) | 801-804 |
Number of pages | 4 |
Journal | Acta Crystallographica Section E: Crystallographic Communications |
Volume | 72 |
DOIs | |
State | Published - Jun 1 2016 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics