Abstract
(Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white).
| Original language | English |
|---|---|
| Pages (from-to) | 8251-8254 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 43 |
| DOIs | |
| State | Published - Oct 13 2008 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Cite this
Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide. / Ohlin, C. A.; Villa, Eric; Fettinger, James C.; Casey, William H.
In: Angewandte Chemie - International Edition, Vol. 47, No. 43, 13.10.2008, p. 8251-8254.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide
AU - Ohlin, C. A.
AU - Villa, Eric
AU - Fettinger, James C.
AU - Casey, William H.
PY - 2008/10/13
Y1 - 2008/10/13
N2 - (Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white).
AB - (Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white).
UR - http://www.scopus.com/inward/record.url?scp=54249168315&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=54249168315&partnerID=8YFLogxK
U2 - 10.1002/anie.200803688
DO - 10.1002/anie.200803688
M3 - Article
VL - 47
SP - 8251
EP - 8254
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 43
ER -