Abstract
(Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white).
Original language | English (US) |
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Pages (from-to) | 8251-8254 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 47 |
Issue number | 43 |
DOIs | |
State | Published - Oct 13 2008 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)