Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide

C. A. Ohlin, Eric Villa, James C. Fettinger, William H. Casey

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

(Figure Presented) Peroxoniobate species are found whenever niobium oxides are employed as photocatalysts or used to sequester radionuclides. The reactions of [Nb6O19]8- and [Nb10O 28]6- with hydrogen peroxide each behave differently, and the first example of a peroxopolyoxoniobate species, [N(CH3) 4]5[H3Nb6O13(O (I)2)6]·9.5 H2O, was structurally characterized (see picture; Nb gray, O red, H white).

Original languageEnglish
Pages (from-to)8251-8254
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number43
DOIs
StatePublished - Oct 13 2008
Externally publishedYes

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Niobium oxide
Photocatalysts
Radioisotopes
Hydrogen peroxide
Hydrogen Peroxide

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide. / Ohlin, C. A.; Villa, Eric; Fettinger, James C.; Casey, William H.

In: Angewandte Chemie - International Edition, Vol. 47, No. 43, 13.10.2008, p. 8251-8254.

Research output: Contribution to journalArticle

Ohlin, C. A. ; Villa, Eric ; Fettinger, James C. ; Casey, William H. / Distinctly different reactivities of two similar polyoxoniobates with hydrogen peroxide. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 43. pp. 8251-8254.
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