Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin, Arthur M. Landis, Bradley W. Smucker, David M. Eichhorn, D. Paul Rillema

Research output: Contribution to journalArticle

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Abstract

The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

Original languageEnglish (US)
Pages (from-to)m1126-m1127
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number8
DOIs
StatePublished - Aug 1 2004

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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