Abstract
The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.
| Original language | English (US) |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 60 |
| Issue number | 8 |
| DOIs | |
| State | Published - Aug 1 2004 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate. / Oshin, Kayode; Landis, Arthur M.; Smucker, Bradley W.; Eichhorn, David M.; Rillema, D. Paul.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 8, 01.08.2004.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate
AU - Oshin, Kayode
AU - Landis, Arthur M.
AU - Smucker, Bradley W.
AU - Eichhorn, David M.
AU - Rillema, D. Paul
PY - 2004/8/1
Y1 - 2004/8/1
N2 - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.
AB - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.
UR - http://www.scopus.com/inward/record.url?scp=18444412299&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=18444412299&partnerID=8YFLogxK
U2 - 10.1107/S1600536804015016
DO - 10.1107/S1600536804015016
M3 - Article
AN - SCOPUS:18444412299
VL - 60
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 8
ER -