Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin; Arthur M. Landis; Bradley W. Smucker; David M. Eichhorn; D. Paul Rillema

doi:10.1107/S1600536804015016

Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin, Arthur M. Landis, Bradley W. Smucker, David M. Eichhorn, D. Paul Rillema

Research output: Contribution to journal › Article

4 Scopus citations

Abstract

The structural properties of [Re(C₅H₅N)(C ₁₀H₈N₂)( CO)₃](CF₃O ₃S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)₅Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

Original language	English (US)
Pages (from-to)	m1126-m1127
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804015016
State	Published - Aug 1 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536804015016

Fingerprint Dive into the research topics of 'Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate'. Together they form a unique fingerprint.

Cite this

Oshin, K., Landis, A. M., Smucker, B. W., Eichhorn, D. M., & Rillema, D. P. (2004). Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate. Acta Crystallographica Section E: Structure Reports Online, 60(8), m1126-m1127. https://doi.org/10.1107/S1600536804015016

@article{ff0ed8068a884f388b5fb57487074090,

title = "Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate",

abstract = "The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.",

author = "Kayode Oshin and Landis, {Arthur M.} and Smucker, {Bradley W.} and Eichhorn, {David M.} and Rillema, {D. Paul}",

year = "2004",

month = aug,

day = "1",

doi = "10.1107/S1600536804015016",

language = "English (US)",

volume = "60",

pages = "m1126--m1127",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

AU - Oshin, Kayode

AU - Landis, Arthur M.

AU - Smucker, Bradley W.

AU - Eichhorn, David M.

AU - Rillema, D. Paul

PY - 2004/8/1

Y1 - 2004/8/1

N2 - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

AB - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

UR - http://www.scopus.com/inward/record.url?scp=18444412299&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=18444412299&partnerID=8YFLogxK

U2 - 10.1107/S1600536804015016

DO - 10.1107/S1600536804015016

M3 - Article

AN - SCOPUS:18444412299

VL - 60

SP - m1126-m1127

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 8

ER -