Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin, Arthur M. Landis, Bradley W. Smucker, David M. Eichhorn, D. Paul Rillema

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number8
DOIs
StatePublished - Aug 1 2004
Externally publishedYes

Fingerprint

Rhenium
rhenium
Carbon Monoxide
Pyridine
pyridines
Ligands
2,2'-Dipyridyl
ligands
Isomers
Cations
Structural properties
dissolving
Ethanol
ethyl alcohol
isomers
Positive ions
cations
Molecules
Geometry
geometry

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate. / Oshin, Kayode; Landis, Arthur M.; Smucker, Bradley W.; Eichhorn, David M.; Rillema, D. Paul.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 8, 01.08.2004.

Research output: Contribution to journalArticle

Oshin, Kayode ; Landis, Arthur M. ; Smucker, Bradley W. ; Eichhorn, David M. ; Rillema, D. Paul. / Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate. In: Acta Crystallographica Section E: Structure Reports Online. 2004 ; Vol. 60, No. 8.
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