Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin; Arthur M. Landis; Bradley W. Smucker; David M. Eichhorn; D. Paul Rillema

doi:10.1107/S1600536804015016

Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin, Arthur M. Landis, Bradley W. Smucker, David M. Eichhorn, D. Paul Rillema

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The structural properties of [Re(C₅H₅N)(C ₁₀H₈N₂)( CO)₃](CF₃O ₃S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)₅Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

Original language	English (US)
Pages (from-to)	m1126-m1127
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804015016
State	Published - Aug 1 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536804015016

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title = "Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate",

abstract = "The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.",

author = "Kayode Oshin and Landis, {Arthur M.} and Smucker, {Bradley W.} and Eichhorn, {David M.} and Rillema, {D. Paul}",

year = "2004",

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doi = "10.1107/S1600536804015016",

language = "English (US)",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

number = "8",

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T1 - Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

AU - Oshin, Kayode

AU - Landis, Arthur M.

AU - Smucker, Bradley W.

AU - Eichhorn, David M.

AU - Rillema, D. Paul

PY - 2004/8/1

Y1 - 2004/8/1

N2 - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

AB - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

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