Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin; Arthur M. Landis; Bradley W. Smucker; David M. Eichhorn; D. Paul Rillema

doi:10.1107/S1600536804015016

Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate

Kayode Oshin, Arthur M. Landis, Bradley W. Smucker, David M. Eichhorn, D. Paul Rillema

Department of Chemistry

Research output: Contribution to journal › Article

4 Scopus citations

Abstract

The structural properties of [Re(C₅H₅N)(C ₁₀H₈N₂)( CO)₃](CF₃O ₃S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)₅Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

Original language	English (US)
Pages (from-to)	m1126-m1127
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804015016
State	Published - Aug 1 2004

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All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Oshin, K., Landis, A. M., Smucker, B. W., Eichhorn, D. M., & Rillema, D. P. (2004). Fac-bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate. Acta Crystallographica Section E: Structure Reports Online, 60(8), m1126-m1127. https://doi.org/10.1107/S1600536804015016

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abstract = "The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.",

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AU - Eichhorn, David M.

AU - Rillema, D. Paul

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AB - The structural properties of [Re(C5H5N)(C 10H8N2)( CO)3](CF3O 3S) were investigated. The compound was prepared as a standard molecule for comparison with the properties of other heterocyclic tricarbonylrhenium (I) complexes containing pyridine as the sixth ligand. The compound was prepared by dissolving Re(CO)5Cl and 2,2'-bipyridine in ethanol and heated at reflux under Ar. The cations shows a distorted octaheral geometry defined by three N donors and three carbonyl ligands that are arranged so that a fac-isomer is formed.

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10.1107/S1600536804015016