In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions

Brendan T. McGrail; Laurent J. Jouffret; Eric M. Villa; Peter C. Burns

doi:10.1557/opl.2012.1127

In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions

Brendan T. McGrail, Laurent J. Jouffret, Eric M. Villa, Peter C. Burns

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Scopus citations

Abstract

By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO₂(O₂)(OH)]₁₆[UO₂(O ₂)₂]₄}^24- (denoted {U _20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

Original language	English (US)
Title of host publication	Actinides and Nuclear Energy Materials
Pages	281-288
Number of pages	8
DOIs	https://doi.org/10.1557/opl.2012.1127
State	Published - Dec 1 2012
Externally published	Yes
Event	2012 MRS Spring Meeting - San Francisco, CA, United States Duration: Apr 9 2012 → Apr 13 2012

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	1444
ISSN (Print)	0272-9172

Other

Other	2012 MRS Spring Meeting
Country	United States
City	San Francisco, CA
Period	4/9/12 → 4/13/12

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1557/opl.2012.1127

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title = "In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions",

abstract = "By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.",

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AU - Jouffret, Laurent J.

AU - Villa, Eric M.

AU - Burns, Peter C.

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Y1 - 2012/12/1

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AB - By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

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BT - Actinides and Nuclear Energy Materials

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