TY - GEN
T1 - In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions
AU - McGrail, Brendan T.
AU - Jouffret, Laurent J.
AU - Villa, Eric M.
AU - Burns, Peter C.
N1 - Funding Information:
This work was supported as part of the Materials Science of Actinides, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0001089.
PY - 2012
Y1 - 2012
N2 - By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.
AB - By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.
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U2 - 10.1557/opl.2012.1127
DO - 10.1557/opl.2012.1127
M3 - Conference contribution
AN - SCOPUS:84875510384
SN - 9781605114217
T3 - Materials Research Society Symposium Proceedings
SP - 281
EP - 288
BT - Actinides and Nuclear Energy Materials
T2 - 2012 MRS Spring Meeting
Y2 - 9 April 2012 through 13 April 2012
ER -