In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions

Brendan T. McGrail; Laurent J. Jouffret; Eric M. Villa; Peter C. Burns

doi:10.1557/opl.2012.1127

In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions

Brendan T. McGrail, Laurent J. Jouffret, Eric M. Villa, Peter C. Burns

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Scopus citations

Abstract

By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO₂(O₂)(OH)]₁₆[UO₂(O ₂)₂]₄}^24- (denoted {U _20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

Original language	English (US)
Title of host publication	Actinides and Nuclear Energy Materials
Pages	281-288
Number of pages	8
DOIs	https://doi.org/10.1557/opl.2012.1127
State	Published - 2012
Externally published	Yes
Event	2012 MRS Spring Meeting - San Francisco, CA, United States Duration: Apr 9 2012 → Apr 13 2012

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	1444
ISSN (Print)	0272-9172

Other

Other	2012 MRS Spring Meeting
Country	United States
City	San Francisco, CA
Period	4/9/12 → 4/13/12

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1557/opl.2012.1127

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Cite this

@inproceedings{2ffc89b99a4b41a6aab0d84eac4b747e,

title = "In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions",

abstract = "By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.",

author = "McGrail, {Brendan T.} and Jouffret, {Laurent J.} and Villa, {Eric M.} and Burns, {Peter C.}",

note = "Funding Information: This work was supported as part of the Materials Science of Actinides, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0001089.; 2012 MRS Spring Meeting ; Conference date: 09-04-2012 Through 13-04-2012",

year = "2012",

doi = "10.1557/opl.2012.1127",

language = "English (US)",

isbn = "9781605114217",

series = "Materials Research Society Symposium Proceedings",

pages = "281--288",

booktitle = "Actinides and Nuclear Energy Materials",

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T1 - In-situ Raman spectroscopy studies of room-temperature and hydrothermal reactions

AU - McGrail, Brendan T.

AU - Jouffret, Laurent J.

AU - Villa, Eric M.

AU - Burns, Peter C.

N1 - Funding Information: This work was supported as part of the Materials Science of Actinides, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0001089.

PY - 2012

Y1 - 2012

N2 - By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

AB - By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(O 2)2]4}24- (denoted {U 20R}) and a coordination polymer made from uranyl ions and 4,4′-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

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DO - 10.1557/opl.2012.1127

M3 - Conference contribution

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T3 - Materials Research Society Symposium Proceedings

SP - 281

EP - 288

BT - Actinides and Nuclear Energy Materials

T2 - 2012 MRS Spring Meeting

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