Mechanism of halide abstraction from (η5-C5H5)Fe(CO)2I by AgBF4

Bruce M. Mattson, William A.G. Graham

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Abstract

The mechanism of halide abstraction from (η5-C5H5)Fe(CO)2I with AgBF4 was investigated by 1H NMR (CDCl3 solvent) and infrared (CH2Cl2 and CHCl3 solvents) spectroscopic methods. (η5-C5H5)Fe(CO)2I initially forms a silver(I) adduct formulated as (η5-C5H5)Fe(CO)2IAg+, which decomposes to yield AgI and, in the presence of excess (η5-C5H5)Fe(CO)2I, the iodine-bridged species [(η5-C5H5)Fe(CO)2] 2IBF4. This material then reacts with a second 0.5 equiv of AgBF4 to yield (η5-C5H5)Fe(CO)2BF4, in which tetrafluoroborate is coordinated.

Original languageEnglish (US)
Pages (from-to)3186-3189
Number of pages4
JournalInorganic Chemistry
Volume20
Issue number10
DOIs
StatePublished - Jan 1 1981
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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