Multidentate 1,2,3-triazole-containing chelators from tandem deprotection/click reactions of (trimethylsilyl)alkynes and comparison of their ruthenium(II) complexes

James T. Fletcher, Benjamin J. Bumgarner, Nicole D. Engels, David A. Skoglund

Research output: Contribution to journalArticle

144 Scopus citations

Abstract

A variation of the copper-catalyzed Huisgen 1,3-dipolar cycloaddition involving a one-pot two-step transformation of trimethylsilyl-protected alkyne reactants was used to prepare multidentate N-heterocyclic chelators containing 1,2,3-triazole rings in high yields. This includes the first reported examples of 1,1′-disubstituted 4,4′-bis(triazole) bidentate chelators derived from click preparations.

Original languageEnglish (US)
Pages (from-to)5430-5433
Number of pages4
JournalOrganometallics
Volume27
Issue number21
DOIs
StatePublished - Nov 10 2008

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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