Abstract
A variation of the copper-catalyzed Huisgen 1,3-dipolar cycloaddition involving a one-pot two-step transformation of trimethylsilyl-protected alkyne reactants was used to prepare multidentate N-heterocyclic chelators containing 1,2,3-triazole rings in high yields. This includes the first reported examples of 1,1′-disubstituted 4,4′-bis(triazole) bidentate chelators derived from click preparations.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5430-5433 |
| Number of pages | 4 |
| Journal | Organometallics |
| Volume | 27 |
| Issue number | 21 |
| DOIs | |
| State | Published - Nov 10 2008 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Fletcher, J. T., Bumgarner, B. J., Engels, N. D., & Skoglund, D. A. (2008). Multidentate 1,2,3-triazole-containing chelators from tandem deprotection/click reactions of (trimethylsilyl)alkynes and comparison of their ruthenium(II) complexes. Organometallics, 27(21), 5430-5433. https://doi.org/10.1021/om800768k