Abstract
Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.
| Original language | English |
|---|---|
| Pages (from-to) | 1161-1170 |
| Number of pages | 10 |
| Journal | Zeitschrift fur Physikalische Chemie |
| Volume | 223 |
| Issue number | 10-11 |
| DOIs | |
| State | Published - 2009 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
Cite this
Nearly constant loss in lithium and LiCl-doped borate glasses. / Sidebottom, David L.; Bassett, M.
In: Zeitschrift fur Physikalische Chemie, Vol. 223, No. 10-11, 2009, p. 1161-1170.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nearly constant loss in lithium and LiCl-doped borate glasses
AU - Sidebottom, David L.
AU - Bassett, M.
PY - 2009
Y1 - 2009
N2 - Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.
AB - Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.
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UR - http://www.scopus.com/inward/citedby.url?scp=75249094205&partnerID=8YFLogxK
U2 - 10.1524/zpch.2009.6071
DO - 10.1524/zpch.2009.6071
M3 - Article
AN - SCOPUS:75249094205
VL - 223
SP - 1161
EP - 1170
JO - Zeitschrift fur Physikalische Chemie
JF - Zeitschrift fur Physikalische Chemie
SN - 0942-9352
IS - 10-11
ER -