Nearly constant loss in lithium and LiCl-doped borate glasses

D. L. Sidebottom; M. Bassett

doi:10.1524/zpch.2009.6071

Nearly constant loss in lithium and LiCl-doped borate glasses

D. L. Sidebottom, M. Bassett

Department of Physics

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Measurements of the complex dielectric permittivity in (Li ₂O)_x(B₂O₃)_100-x, and halide-doped (Li₂O)_x (LiCl)_y(B ₂O₃)_100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li₂O)_x(B₂O ₃)_100-x is largely ionic in origin for these materials and increases in proportion to the Li₂O content. However, at low Li ₂O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.

Original language	English (US)
Pages (from-to)	1161-1170
Number of pages	10
Journal	Zeitschrift fur Physikalische Chemie
Volume	223
Issue number	10-11
DOIs	https://doi.org/10.1524/zpch.2009.6071
State	Published - 2009

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1524/zpch.2009.6071

Cite this

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title = "Nearly constant loss in lithium and LiCl-doped borate glasses",

abstract = "Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.",

author = "Sidebottom, {D. L.} and M. Bassett",

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doi = "10.1524/zpch.2009.6071",

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pages = "1161--1170",

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T1 - Nearly constant loss in lithium and LiCl-doped borate glasses

AU - Sidebottom, D. L.

AU - Bassett, M.

N1 - Funding Information: This research was supported by an award from Research Corporation (grant No. CC6641).

PY - 2009

Y1 - 2009

N2 - Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.

AB - Measurements of the complex dielectric permittivity in (Li 2O)x(B2O3)100-x, and halide-doped (Li2O)x (LiCl)y(B 2O3)100-x-y glasses conducted in the nearly constant loss (NCL) regime at low temperatures are reported. Scaling properties reveal that the NCL in (Li2O)x(B2O 3)100-x is largely ionic in origin for these materials and increases in proportion to the Li2O content. However, at low Li 2O content, the NCL becomes dominated by a non-ionic loss arising from the borate network or other impurity polarizations. Halide doping is seen to produce an additional enhancement of the NCL that is consistent with its known enhancement of the bulk conduction.

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Nearly constant loss in lithium and LiCl-doped borate glasses

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