Abstract
A family of four new neodymium(III) compounds containing either sulfite or a mixture of hydrogen-sulfate and sulfite ligands has been hydrothermally synthesized. The low solubility of lanthanide sulfite compounds has, in the past, made the isolation of single-crystalline products difficult. To obtain these phases, sodium sulfite (Na2SO3) and sodium bisulfite (NaHSO3) were employed as both anion sources and pH regulators. The in situ oxidation of sulfite to sulfate was controlled by dictating the pH of the starting solutions with these ligands. Sulfites were found to form at a neutral pH, whereas, when the pH was increased, the oxidation of sulfite to sulfate was observed in the crystalline products. The products discussed herein reveal the pH controlled process of in situ oxidation in these hydrothermal reactions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5332-5341 |
| Number of pages | 10 |
| Journal | Crystal Growth and Design |
| Volume | 18 |
| Issue number | 9 |
| DOIs | |
| State | Published - Sep 5 2018 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
PH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites. / Dovgan, Jakob T.; Polinski, Matthew J.; Mercado, Brandon Q.; Villa, Eric.
In: Crystal Growth and Design, Vol. 18, No. 9, 05.09.2018, p. 5332-5341.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - PH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites
AU - Dovgan, Jakob T.
AU - Polinski, Matthew J.
AU - Mercado, Brandon Q.
AU - Villa, Eric
PY - 2018/9/5
Y1 - 2018/9/5
N2 - A family of four new neodymium(III) compounds containing either sulfite or a mixture of hydrogen-sulfate and sulfite ligands has been hydrothermally synthesized. The low solubility of lanthanide sulfite compounds has, in the past, made the isolation of single-crystalline products difficult. To obtain these phases, sodium sulfite (Na2SO3) and sodium bisulfite (NaHSO3) were employed as both anion sources and pH regulators. The in situ oxidation of sulfite to sulfate was controlled by dictating the pH of the starting solutions with these ligands. Sulfites were found to form at a neutral pH, whereas, when the pH was increased, the oxidation of sulfite to sulfate was observed in the crystalline products. The products discussed herein reveal the pH controlled process of in situ oxidation in these hydrothermal reactions.
AB - A family of four new neodymium(III) compounds containing either sulfite or a mixture of hydrogen-sulfate and sulfite ligands has been hydrothermally synthesized. The low solubility of lanthanide sulfite compounds has, in the past, made the isolation of single-crystalline products difficult. To obtain these phases, sodium sulfite (Na2SO3) and sodium bisulfite (NaHSO3) were employed as both anion sources and pH regulators. The in situ oxidation of sulfite to sulfate was controlled by dictating the pH of the starting solutions with these ligands. Sulfites were found to form at a neutral pH, whereas, when the pH was increased, the oxidation of sulfite to sulfate was observed in the crystalline products. The products discussed herein reveal the pH controlled process of in situ oxidation in these hydrothermal reactions.
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UR - http://www.scopus.com/inward/citedby.url?scp=85052291866&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.8b00769
DO - 10.1021/acs.cgd.8b00769
M3 - Article
VL - 18
SP - 5332
EP - 5341
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 9
ER -