Abstract
A sequence of two organic reactions involving gas-phase heterogeneous catalysis suitable for use as a laboratory experiment is outlined. In the first reaction, 2-propanol is converted to propene using alumina beads as the catalyst. The product gas is purified with a mini-cold trap. In the second reaction, propene is hydrogenated to propane using a palladium catalyst in nearly 100% yield. The experiment demonstrates continuous-flow, closed-system gas-phase reactions of fundamental importance in chemical industry. It also demonstrates the power of NMR in the context for which it actually is used by organic and inorganic chemists: structural confirmation and analysis.
| Original language | English |
|---|---|
| Pages (from-to) | 421-424 |
| Number of pages | 4 |
| Journal | Journal of Chemical Education |
| Volume | 83 |
| Issue number | 3 |
| State | Published - Mar 2006 |
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All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Education
Cite this
Propanol to propane : An advanced laboratory experiment using heterogeneous catalysts for two successive gas-phase reactions. / Mattson, Bruce M.; Hulce, Martin; Cheng, Wes; Greimann, Jaclyn; Hoette, Trisha; Menzel, Peter.
In: Journal of Chemical Education, Vol. 83, No. 3, 03.2006, p. 421-424.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Propanol to propane
T2 - An advanced laboratory experiment using heterogeneous catalysts for two successive gas-phase reactions
AU - Mattson, Bruce M.
AU - Hulce, Martin
AU - Cheng, Wes
AU - Greimann, Jaclyn
AU - Hoette, Trisha
AU - Menzel, Peter
PY - 2006/3
Y1 - 2006/3
N2 - A sequence of two organic reactions involving gas-phase heterogeneous catalysis suitable for use as a laboratory experiment is outlined. In the first reaction, 2-propanol is converted to propene using alumina beads as the catalyst. The product gas is purified with a mini-cold trap. In the second reaction, propene is hydrogenated to propane using a palladium catalyst in nearly 100% yield. The experiment demonstrates continuous-flow, closed-system gas-phase reactions of fundamental importance in chemical industry. It also demonstrates the power of NMR in the context for which it actually is used by organic and inorganic chemists: structural confirmation and analysis.
AB - A sequence of two organic reactions involving gas-phase heterogeneous catalysis suitable for use as a laboratory experiment is outlined. In the first reaction, 2-propanol is converted to propene using alumina beads as the catalyst. The product gas is purified with a mini-cold trap. In the second reaction, propene is hydrogenated to propane using a palladium catalyst in nearly 100% yield. The experiment demonstrates continuous-flow, closed-system gas-phase reactions of fundamental importance in chemical industry. It also demonstrates the power of NMR in the context for which it actually is used by organic and inorganic chemists: structural confirmation and analysis.
UR - http://www.scopus.com/inward/record.url?scp=33644667128&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33644667128&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33644667128
VL - 83
SP - 421
EP - 424
JO - Journal of Chemical Education
JF - Journal of Chemical Education
SN - 0021-9584
IS - 3
ER -