Reaction dynamics of the decaniobate ion [HxNb 10O28](6-x)- in water

Eric M. Villa, C. André Ohlin, Edina Balogh, Travis M. Anderson, May D. Nyman, William H. Casey

Research output: Contribution to journalArticle

82 Scopus citations

Abstract

(Figure Presented) The nanometer-size title cluster is unique in that it reacts slowly enough in water that one can simultaneously observe steady-state oxygen-isotope exchanges and dissociation pathways (see scheme; O red, Nb green), leading to conceptual advances in both geochemistry and polyoxometalate chemistry.

Original languageEnglish (US)
Pages (from-to)4844-4846
Number of pages3
JournalAngewandte Chemie - International Edition
Volume47
Issue number26
DOIs
StatePublished - Jun 16 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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