Reaction dynamics of the decaniobate ion [HxNb 10O28](6-x)- in water

Eric M. Villa; C. André Ohlin; Edina Balogh; Travis M. Anderson; May D. Nyman; William H. Casey

doi:10.1002/anie.200801125

Reaction dynamics of the decaniobate ion [H_xNb ₁₀O₂₈]^(6-x)- in water

Eric M. Villa, C. André Ohlin, Edina Balogh, Travis M. Anderson, May D. Nyman, William H. Casey

Research output: Contribution to journal › Article

82 Scopus citations

Abstract

(Figure Presented) The nanometer-size title cluster is unique in that it reacts slowly enough in water that one can simultaneously observe steady-state oxygen-isotope exchanges and dissociation pathways (see scheme; O red, Nb green), leading to conceptual advances in both geochemistry and polyoxometalate chemistry.

Original language	English (US)
Pages (from-to)	4844-4846
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	26
DOIs	https://doi.org/10.1002/anie.200801125
State	Published - Jun 16 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200801125

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Villa, E. M., Ohlin, C. A., Balogh, E., Anderson, T. M., Nyman, M. D., & Casey, W. H. (2008). Reaction dynamics of the decaniobate ion [H_xNb ₁₀O₂₈]^(6-x)- in water. Angewandte Chemie - International Edition, 47(26), 4844-4846. https://doi.org/10.1002/anie.200801125

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AU - Nyman, May D.

AU - Casey, William H.

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