Abstract
Three new alkaline earth (AE) uranyl phosphites and one barium uranium(iv) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO 22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.
| Original language | English |
|---|---|
| Pages (from-to) | 9637-9644 |
| Number of pages | 8 |
| Journal | Dalton Transactions |
| Volume | 42 |
| Issue number | 26 |
| DOIs | |
| State | Published - Jul 14 2013 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Inorganic Chemistry
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Structural changes within the alkaline earth uranyl phosphites. / Villa, Eric; Diwu, Juan; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.
In: Dalton Transactions, Vol. 42, No. 26, 14.07.2013, p. 9637-9644.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structural changes within the alkaline earth uranyl phosphites
AU - Villa, Eric
AU - Diwu, Juan
AU - Alekseev, Evgeny V.
AU - Depmeier, Wulf
AU - Albrecht-Schmitt, Thomas E.
PY - 2013/7/14
Y1 - 2013/7/14
N2 - Three new alkaline earth (AE) uranyl phosphites and one barium uranium(iv) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO 22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.
AB - Three new alkaline earth (AE) uranyl phosphites and one barium uranium(iv) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO 22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.
UR - http://www.scopus.com/inward/record.url?scp=84881057877&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84881057877&partnerID=8YFLogxK
U2 - 10.1039/c3dt50769f
DO - 10.1039/c3dt50769f
M3 - Article
VL - 42
SP - 9637
EP - 9644
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 26
ER -