Structural changes within the alkaline earth uranyl phosphites

Eric Villa, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht-Schmitt

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Three new alkaline earth (AE) uranyl phosphites and one barium uranium(iv) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO 22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.

Original languageEnglish
Pages (from-to)9637-9644
Number of pages8
JournalDalton Transactions
Volume42
Issue number26
DOIs
StatePublished - Jul 14 2013
Externally publishedYes

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Phosphites
Cations
Earth (planet)
Calcium Compounds
Uranium
Carbonates
Barium
Salts
Phosphates

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Villa, E., Diwu, J., Alekseev, E. V., Depmeier, W., & Albrecht-Schmitt, T. E. (2013). Structural changes within the alkaline earth uranyl phosphites. Dalton Transactions, 42(26), 9637-9644. https://doi.org/10.1039/c3dt50769f

Structural changes within the alkaline earth uranyl phosphites. / Villa, Eric; Diwu, Juan; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.

In: Dalton Transactions, Vol. 42, No. 26, 14.07.2013, p. 9637-9644.

Research output: Contribution to journalArticle

Villa, E, Diwu, J, Alekseev, EV, Depmeier, W & Albrecht-Schmitt, TE 2013, 'Structural changes within the alkaline earth uranyl phosphites', Dalton Transactions, vol. 42, no. 26, pp. 9637-9644. https://doi.org/10.1039/c3dt50769f
Villa E, Diwu J, Alekseev EV, Depmeier W, Albrecht-Schmitt TE. Structural changes within the alkaline earth uranyl phosphites. Dalton Transactions. 2013 Jul 14;42(26):9637-9644. https://doi.org/10.1039/c3dt50769f
Villa, Eric ; Diwu, Juan ; Alekseev, Evgeny V. ; Depmeier, Wulf ; Albrecht-Schmitt, Thomas E. / Structural changes within the alkaline earth uranyl phosphites. In: Dalton Transactions. 2013 ; Vol. 42, No. 26. pp. 9637-9644.
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