Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure

Jakob T. Dovgan; Matthew J. Polinski; Eric M. Villa

doi:10.1002/zaac.201800314

Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure

Jakob T. Dovgan, Matthew J. Polinski, Eric M. Villa

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The first lanthanide sulfite compound with a secondary ligand, Nd(SO₃)(C₂H₃O₂), was hydrothermally synthesized and solved with single-crystal X-ray diffraction. In order to prevent the facile oxidation of the sulfite to sulfate, careful control of both pH and reaction temperature were required for successful synthesis of the title compound; even slight changes in conditions allow for the facile oxidation of sulfite to sulfate and yields the known [Nd(C₂H₃O₂)(SO₄)(H₂O)₂] structure. This two-dimensional sheet topology further expands the chemistry of lanthanide sulfite extended structures and also allows for easy structural comparisons to other lanthanide sulfite compounds and the above mentioned neodymium sulfate-acetate compound.

Original language	English (US)
Pages (from-to)	31-35
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	645
Issue number	1
DOIs	https://doi.org/10.1002/zaac.201800314
State	Published - Jan 15 2019

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1002/zaac.201800314

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abstract = "The first lanthanide sulfite compound with a secondary ligand, Nd(SO3)(C2H3O2), was hydrothermally synthesized and solved with single-crystal X-ray diffraction. In order to prevent the facile oxidation of the sulfite to sulfate, careful control of both pH and reaction temperature were required for successful synthesis of the title compound; even slight changes in conditions allow for the facile oxidation of sulfite to sulfate and yields the known [Nd(C2H3O2)(SO4)(H2O)2] structure. This two-dimensional sheet topology further expands the chemistry of lanthanide sulfite extended structures and also allows for easy structural comparisons to other lanthanide sulfite compounds and the above mentioned neodymium sulfate-acetate compound.",

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note = "Funding Information: Funding for the project was provided by Creighton University. The authors would like to thank Creighton University and the Creighton University Chemistry Department for supporting undergraduate research. Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Polinski, Matthew J.

AU - Villa, Eric M.

N1 - Funding Information: Funding for the project was provided by Creighton University. The authors would like to thank Creighton University and the Creighton University Chemistry Department for supporting undergraduate research. Publisher Copyright: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2019/1/15

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N2 - The first lanthanide sulfite compound with a secondary ligand, Nd(SO3)(C2H3O2), was hydrothermally synthesized and solved with single-crystal X-ray diffraction. In order to prevent the facile oxidation of the sulfite to sulfate, careful control of both pH and reaction temperature were required for successful synthesis of the title compound; even slight changes in conditions allow for the facile oxidation of sulfite to sulfate and yields the known [Nd(C2H3O2)(SO4)(H2O)2] structure. This two-dimensional sheet topology further expands the chemistry of lanthanide sulfite extended structures and also allows for easy structural comparisons to other lanthanide sulfite compounds and the above mentioned neodymium sulfate-acetate compound.

AB - The first lanthanide sulfite compound with a secondary ligand, Nd(SO3)(C2H3O2), was hydrothermally synthesized and solved with single-crystal X-ray diffraction. In order to prevent the facile oxidation of the sulfite to sulfate, careful control of both pH and reaction temperature were required for successful synthesis of the title compound; even slight changes in conditions allow for the facile oxidation of sulfite to sulfate and yields the known [Nd(C2H3O2)(SO4)(H2O)2] structure. This two-dimensional sheet topology further expands the chemistry of lanthanide sulfite extended structures and also allows for easy structural comparisons to other lanthanide sulfite compounds and the above mentioned neodymium sulfate-acetate compound.

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Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure

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