Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure

Jakob T. Dovgan, Matthew J. Polinski, Eric Villa

Research output: Contribution to journal › Article

Abstract

The first lanthanide sulfite compound with a secondary ligand, Nd(SO3)(C2H3O2), was hydrothermally synthesized and solved with single-crystal X-ray diffraction. In order to prevent the facile oxidation of the sulfite to sulfate, careful control of both pH and reaction temperature were required for successful synthesis of the title compound; even slight changes in conditions allow for the facile oxidation of sulfite to sulfate and yields the known [Nd(C2H3O2)(SO4)(H2O)2] structure. This two-dimensional sheet topology further expands the chemistry of lanthanide sulfite extended structures and also allows for easy structural comparisons to other lanthanide sulfite compounds and the above mentioned neodymium sulfate-acetate compound.

Original languageEnglish (US)
JournalZeitschrift fur Anorganische und Allgemeine Chemie
DOIs
StateAccepted/In press - Jan 1 2018

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Neodymium
Sulfites
Acetates
Crystal structure
Lanthanoid Series Elements
Sulfates
Oxidation
Topology
Single crystals
Ligands
X ray diffraction

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure. / Dovgan, Jakob T.; Polinski, Matthew J.; Villa, Eric.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, 01.01.2018.

Research output: Contribution to journal › Article

Dovgan, JT, Polinski, MJ & Villa, E 2018, 'Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure', Zeitschrift fur Anorganische und Allgemeine Chemie. https://doi.org/10.1002/zaac.201800314
Dovgan JT, Polinski MJ, Villa E. Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure. Zeitschrift fur Anorganische und Allgemeine Chemie. 2018 Jan 1. https://doi.org/10.1002/zaac.201800314
Dovgan, Jakob T. ; Polinski, Matthew J. ; Villa, Eric. / Synthesis, Characterization, and Structural Comparisons of the First Neodymium(III) Sulfite-Acetate Crystal Structure. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2018.
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