The [Ti12Nb6O44]10- ion - A new type of polyoxometalate structure

C. André Ohlin, Eric Villa, James C. Fettinger, William H. Casey

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH3)4] 10[Ti12Nb6O44], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti12Nb6O44]10-). (Graph Presented)

Original languageEnglish
Pages (from-to)5634-5636
Number of pages3
JournalAngewandte Chemie - International Edition
Volume47
Issue number30
DOIs
StatePublished - Jul 14 2008
Externally publishedYes

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X ray crystallography
Mass spectrometry
Ions
Water
polyoxometalate I

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Cite this

The [Ti12Nb6O44]10- ion - A new type of polyoxometalate structure. / Ohlin, C. André; Villa, Eric; Fettinger, James C.; Casey, William H.

In: Angewandte Chemie - International Edition, Vol. 47, No. 30, 14.07.2008, p. 5634-5636.

Research output: Contribution to journalArticle

Ohlin, C. André ; Villa, Eric ; Fettinger, James C. ; Casey, William H. / The [Ti12Nb6O44]10- ion - A new type of polyoxometalate structure. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 30. pp. 5634-5636.
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