The [Ti12Nb6O44]10- ion - A new type of polyoxometalate structure

C. André Ohlin, Eric M. Villa, James C. Fettinger, William H. Casey

Research output: Contribution to journalArticle

76 Scopus citations

Abstract

An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH3)4] 10[Ti12Nb6O44], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti12Nb6O44]10-). (Graph Presented)

Original languageEnglish (US)
Pages (from-to)5634-5636
Number of pages3
JournalAngewandte Chemie - International Edition
Volume47
Issue number30
DOIs
StatePublished - Jul 14 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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