Abstract
Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.
Original language | English (US) |
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Pages (from-to) | 11949-11954 |
Number of pages | 6 |
Journal | Inorganic Chemistry |
Volume | 51 |
Issue number | 21 |
DOIs | |
State | Published - Nov 5 2012 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry