Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

Original languageEnglish
Pages (from-to)11949-11954
Number of pages6
JournalInorganic Chemistry
Volume51
Issue number21
DOIs
StatePublished - Nov 5 2012
Externally publishedYes

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Cerium
Plutonium
plutonium
cerium
halides
Anions
Diffraction
Single crystals
anions
single crystals
diffraction
tellurous acid

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br). / Lin, Jian; Cross, Justin N.; Diwu, Juan; Polinski, Matthew J.; Villa, Eric; Albrecht-Schmitt, Thomas E.

In: Inorganic Chemistry, Vol. 51, No. 21, 05.11.2012, p. 11949-11954.

Research output: Contribution to journalArticle

Lin, Jian ; Cross, Justin N. ; Diwu, Juan ; Polinski, Matthew J. ; Villa, Eric ; Albrecht-Schmitt, Thomas E. / Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br). In: Inorganic Chemistry. 2012 ; Vol. 51, No. 21. pp. 11949-11954.
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