Abstract
Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 11949-11954 |
| Number of pages | 6 |
| Journal | Inorganic Chemistry |
| Volume | 51 |
| Issue number | 21 |
| DOIs | |
| State | Published - Nov 5 2012 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Lin, J., Cross, J. N., Diwu, J., Polinski, M. J., Villa, E. M., & Albrecht-Schmitt, T. E. (2012). Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br). Inorganic Chemistry, 51(21), 11949-11954. https://doi.org/10.1021/ic301846g