Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin; Justin N. Cross; Juan Diwu; Matthew J. Polinski; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article › peer-review

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Abstract

Four isotypic cationic layered materials, [Pu ₂Te ₄O ₁₁]Cl ₂, [Ce ₂Te ₄O ₁₁]Cl ₂, [Zr ₂Te ₄O ₁₁] Cl ₂, and [Zr ₂Te ₄O ₁₁]Br ₂, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu ^IV, Ce ^IV, and Zr ^IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

Original language	English (US)
Pages (from-to)	11949-11954
Number of pages	6
Journal	Inorganic Chemistry
Volume	51
Issue number	21
DOIs	https://doi.org/10.1021/ic301846g
State	Published - Nov 5 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)",

abstract = "Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.",

author = "Jian Lin and Cross, {Justin N.} and Juan Diwu and Polinski, {Matthew J.} and Villa, {Eric M.} and Albrecht-Schmitt, {Thomas E.}",

year = "2012",

month = nov,

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doi = "10.1021/ic301846g",

language = "English (US)",

volume = "51",

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journal = "Inorganic Chemistry",

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T1 - Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

AU - Lin, Jian

AU - Cross, Justin N.

AU - Diwu, Juan

AU - Polinski, Matthew J.

AU - Villa, Eric M.

AU - Albrecht-Schmitt, Thomas E.

PY - 2012/11/5

Y1 - 2012/11/5

N2 - Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

AB - Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

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Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

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