Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin; Justin N. Cross; Juan Diwu; Matthew J. Polinski; Eric Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric Villa, Thomas E. Albrecht-Schmitt

Research output: Contribution to journal › Article

24 Citations (Scopus)

Abstract

Four isotypic cationic layered materials, [Pu ₂Te ₄O ₁₁]Cl ₂, [Ce ₂Te ₄O ₁₁]Cl ₂, [Zr ₂Te ₄O ₁₁] Cl ₂, and [Zr ₂Te ₄O ₁₁]Br ₂, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu ^IV, Ce ^IV, and Zr ^IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

Original language	English
Pages (from-to)	11949-11954
Number of pages	6
Journal	Inorganic Chemistry
Volume	51
Issue number	21
DOIs	https://doi.org/10.1021/ic301846g
State	Published - Nov 5 2012
Externally published	Yes

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Cerium

Plutonium

plutonium

cerium

halides

Anions

Diffraction

Single crystals

anions

single crystals

diffraction

tellurous acid

All Science Journal Classification (ASJC) codes

Inorganic Chemistry
Physical and Theoretical Chemistry

Cite this

Lin, J., Cross, J. N., Diwu, J., Polinski, M. J., Villa, E., & Albrecht-Schmitt, T. E. (2012). Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). Inorganic Chemistry, 51(21), 11949-11954. https://doi.org/10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). / Lin, Jian; Cross, Justin N.; Diwu, Juan; Polinski, Matthew J.; Villa, Eric; Albrecht-Schmitt, Thomas E.

In: Inorganic Chemistry, Vol. 51, No. 21, 05.11.2012, p. 11949-11954.

Research output: Contribution to journal › Article

Lin, J, Cross, JN, Diwu, J, Polinski, MJ, Villa, E & Albrecht-Schmitt, TE 2012, 'Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)', Inorganic Chemistry, vol. 51, no. 21, pp. 11949-11954. https://doi.org/10.1021/ic301846g

Lin J, Cross JN, Diwu J, Polinski MJ, Villa E, Albrecht-Schmitt TE. Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). Inorganic Chemistry. 2012 Nov 5;51(21):11949-11954. https://doi.org/10.1021/ic301846g

Lin, Jian ; Cross, Justin N. ; Diwu, Juan ; Polinski, Matthew J. ; Villa, Eric ; Albrecht-Schmitt, Thomas E. / Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). In: Inorganic Chemistry. 2012 ; Vol. 51, No. 21. pp. 11949-11954.

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abstract = "Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.",

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10.1021/ic301846g