Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M 2Te 4O 11]X 2 (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin; Justin N. Cross; Juan Diwu; Matthew J. Polinski; Eric M. Villa; Thomas E. Albrecht-Schmitt

doi:10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br)

Jian Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht-Schmitt

Department of Chemistry

Research output: Contribution to journal › Article

24 Scopus citations

Abstract

Four isotypic cationic layered materials, [Pu ₂Te ₄O ₁₁]Cl ₂, [Ce ₂Te ₄O ₁₁]Cl ₂, [Zr ₂Te ₄O ₁₁] Cl ₂, and [Zr ₂Te ₄O ₁₁]Br ₂, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu ^IV, Ce ^IV, and Zr ^IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.

Original language	English (US)
Pages (from-to)	11949-11954
Number of pages	6
Journal	Inorganic Chemistry
Volume	51
Issue number	21
DOIs	https://doi.org/10.1021/ic301846g
State	Published - Nov 5 2012

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All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

Lin, J., Cross, J. N., Diwu, J., Polinski, M. J., Villa, E. M., & Albrecht-Schmitt, T. E. (2012). Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). Inorganic Chemistry, 51(21), 11949-11954. https://doi.org/10.1021/ic301846g

Unusual coordination for plutonium(IV), cerium(IV), and zirconium(IV) in the cationic layered materials [M ₂Te ₄O ₁₁]X ₂ (M = Pu, Ce, Zr; X = Cl, Br). / Lin, Jian; Cross, Justin N.; Diwu, Juan; Polinski, Matthew J.; Villa, Eric M.; Albrecht-Schmitt, Thomas E.

In: Inorganic Chemistry, Vol. 51, No. 21, 05.11.2012, p. 11949-11954.

Research output: Contribution to journal › Article

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abstract = "Four isotypic cationic layered materials, [Pu 2Te 4O 11]Cl 2, [Ce 2Te 4O 11]Cl 2, [Zr 2Te 4O 11] Cl 2, and [Zr 2Te 4O 11]Br 2, have been prepared under hydrothermal conditions. Single crystal diffraction studies reveal that these materials possess cationic Pu/Ce/Zr tellurite layers with halides as interlamellar charge-balancing anions. The Pu IV, Ce IV, and Zr IV centers of the cationic layers exhibit a quite rare pentagonal bipyramid coordination environment.",

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10.1021/ic301846g