Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions: A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction

Journi E. Burke; Emily A. Khoury; Grant J. Koskay; Christopher J. Lewarne; Emily A. Reeson; Katherine L. Sandquist; Kayode Oshin; Matthias Zeller

doi:10.1021/acs.jchemed.8b00721

Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions: A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction

Journi E. Burke, Emily A. Khoury, Grant J. Koskay, Christopher J. Lewarne, Emily A. Reeson, Katherine L. Sandquist, Kayode Oshin, Matthias Zeller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

This laboratory experiment demonstrates the important utility of transition-metal complexes as catalysts in the addition reaction of carbon tetrabromide (CBr₄) to select alkenes. This application offers students the opportunity to understand why transition-metal complexes are worth synthesizing. The experiment builds on fundamental theories presented during first-year general chemistry courses and integrates concepts taught in organic chemistry, inorganic chemistry, organometallics, and instrumental analysis. It incorporates some advanced laboratory practices for students to assimilate with, such as literature searches and interpretation; organometallic compound analysis; catalysis experiment design; reaction mechanisms; NMR spectroscopy with comprehensive spectra interpretation; and X-ray crystallography.

Original language	English (US)
Journal	Journal of chemical education
DOIs	https://doi.org/10.1021/acs.jchemed.8b00721
State	Published - Jan 1 2019

All Science Journal Classification (ASJC) codes

Chemistry(all)
Education

Access to Document

10.1021/acs.jchemed.8b00721

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Burke, J. E., Khoury, E. A., Koskay, G. J., Lewarne, C. J., Reeson, E. A., Sandquist, K. L., Oshin, K., & Zeller, M. (2019). Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions: A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction. Journal of chemical education. https://doi.org/10.1021/acs.jchemed.8b00721

Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions : A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction. / Burke, Journi E.; Khoury, Emily A.; Koskay, Grant J.; Lewarne, Christopher J.; Reeson, Emily A.; Sandquist, Katherine L.; Oshin, Kayode; Zeller, Matthias.

In: Journal of chemical education, 01.01.2019.

Research output: Contribution to journal › Article › peer-review

Burke, Journi E. ; Khoury, Emily A. ; Koskay, Grant J. ; Lewarne, Christopher J. ; Reeson, Emily A. ; Sandquist, Katherine L. ; Oshin, Kayode ; Zeller, Matthias. / Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions : A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction. In: Journal of chemical education. 2019.

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