Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions: A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction

Journi E. Burke, Emily A. Khoury, Grant J. Koskay, Christopher J. Lewarne, Emily A. Reeson, Katherine L. Sandquist, Kayode Oshin, Matthias Zeller

Research output: Contribution to journalArticle

Abstract

This laboratory experiment demonstrates the important utility of transition-metal complexes as catalysts in the addition reaction of carbon tetrabromide (CBr4) to select alkenes. This application offers students the opportunity to understand why transition-metal complexes are worth synthesizing. The experiment builds on fundamental theories presented during first-year general chemistry courses and integrates concepts taught in organic chemistry, inorganic chemistry, organometallics, and instrumental analysis. It incorporates some advanced laboratory practices for students to assimilate with, such as literature searches and interpretation; organometallic compound analysis; catalysis experiment design; reaction mechanisms; NMR spectroscopy with comprehensive spectra interpretation; and X-ray crystallography.

Original languageEnglish (US)
JournalJournal of chemical education
DOIs
StatePublished - Jan 1 2019

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Addition reactions
Coordination Complexes
laboratory experiment
Transition metals
chemistry
Catalysts
Organometallic Compounds
Students
interpretation
Experiments
X ray crystallography
experiment
Alkenes
Organometallics
Catalysis
Nuclear magnetic resonance spectroscopy
student

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Education

Cite this

Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions : A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction. / Burke, Journi E.; Khoury, Emily A.; Koskay, Grant J.; Lewarne, Christopher J.; Reeson, Emily A.; Sandquist, Katherine L.; Oshin, Kayode; Zeller, Matthias.

In: Journal of chemical education, 01.01.2019.

Research output: Contribution to journalArticle

Burke, Journi E. ; Khoury, Emily A. ; Koskay, Grant J. ; Lewarne, Christopher J. ; Reeson, Emily A. ; Sandquist, Katherine L. ; Oshin, Kayode ; Zeller, Matthias. / Using Transition-Metal Complexes as Catalysts for Radical Addition Reactions : A Laboratory Experiment Demonstrating the Important Role of Catalysts in an Organic Transformation Reaction. In: Journal of chemical education. 2019.
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