X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond

Louis H. Pignolet; Bruce M. Mattson

doi:10.1039/C39750000049

X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond

Louis H. Pignolet, Bruce M. Mattson

Research output: Contribution to journal › Article

6 Scopus citations

Abstract

Reaction of tris-(NN-diethyldithiocarbamato)-ruthenium(III) [Ru(Et ₂dtc)₃] with boron trifluoride in benzene solution open to the air gives a dark red ben-zene-insoluble compound which has been found by X-ray crystallography to be [Ru₂(Et₂dtc)₅] ⁺BF₄^- with two types of bridging dithiocarbamato-ligands.

Original language	English
Pages (from-to)	49-50
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39750000049
Publication status	Published - 1975
Externally published	Yes

Fingerprint

All Science Journal Classification (ASJC) codes

Molecular Medicine

Cite this

Pignolet, L. H., & Mattson, B. M. (1975). X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond. Journal of the Chemical Society, Chemical Communications, (2), 49-50. https://doi.org/10.1039/C39750000049

@article{cb263087ddda4372ace01376b4e469b5,

title = "X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond",

abstract = "Reaction of tris-(NN-diethyldithiocarbamato)-ruthenium(III) [Ru(Et 2dtc)3] with boron trifluoride in benzene solution open to the air gives a dark red ben-zene-insoluble compound which has been found by X-ray crystallography to be [Ru2(Et2dtc)5] +BF4- with two types of bridging dithiocarbamato-ligands.",

author = "Pignolet, {Louis H.} and Mattson, {Bruce M.}",

year = "1975",

doi = "10.1039/C39750000049",

language = "English",

pages = "49--50",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond

AU - Pignolet, Louis H.

AU - Mattson, Bruce M.

PY - 1975

Y1 - 1975

N2 - Reaction of tris-(NN-diethyldithiocarbamato)-ruthenium(III) [Ru(Et 2dtc)3] with boron trifluoride in benzene solution open to the air gives a dark red ben-zene-insoluble compound which has been found by X-ray crystallography to be [Ru2(Et2dtc)5] +BF4- with two types of bridging dithiocarbamato-ligands.

AB - Reaction of tris-(NN-diethyldithiocarbamato)-ruthenium(III) [Ru(Et 2dtc)3] with boron trifluoride in benzene solution open to the air gives a dark red ben-zene-insoluble compound which has been found by X-ray crystallography to be [Ru2(Et2dtc)5] +BF4- with two types of bridging dithiocarbamato-ligands.

UR - http://www.scopus.com/inward/record.url?scp=37049121100&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049121100&partnerID=8YFLogxK

U2 - 10.1039/C39750000049

DO - 10.1039/C39750000049

M3 - Article

AN - SCOPUS:37049121100

SP - 49

EP - 50

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 2

ER -

Access to Document

10.1039/C39750000049