@article{cb263087ddda4372ace01376b4e469b5,
title = "X-Ray structure and characterization of a novel dithiocarbamato-complex of ruthenium(III) containing a metal-metal bond",
abstract = "Reaction of tris-(NN-diethyldithiocarbamato)-ruthenium(III) [Ru(Et 2dtc)3] with boron trifluoride in benzene solution open to the air gives a dark red ben-zene-insoluble compound which has been found by X-ray crystallography to be [Ru2(Et2dtc)5] +BF4- with two types of bridging dithiocarbamato-ligands.",
author = "Pignolet, {Louis H.} and Mattson, {Bruce M.}",
note = "Funding Information: We thank the National Science Foundation, the Research Corporation, and the University of Minnesota Computer Center for support of this work. (Received, 28th October 1974; Corn. 1328.) p Molecular weight results indicate some molecular association at concentrations greater than 1 x 10-3 M. This has also been observed by Gahan and O'Connor.5 1 R. M. Golding, C. M. Harris, K. J. Jessop, and W. C. Tennant, Austral. J. Chem., 1972, 25, 2567.* R. L. Martin, N. M. Rohde, G. B. Robertson, and D. Taylor, J. Amer. Chem. SOC.,1974,96, 3647. 8 K. L. Brown, Cryst. Struct. Comm., 1974, 3, 493. Q E. A. Pasek and D. K. Straub, Inorg. Chem., 1972, 11, 269. 5 L. R. Gahan and M. J. O'Connor, J.C.S. Chem. Cornm., 1974, 67. M. C. Palazzotto, D. J. Duffy,B. L. Edgar, L. Que, Jr., and L. H. Pignolet, J. Amer. Chem. SOC.,1973, 95, 4537. 7 G. S. Patterson and R. H. Holm, Inovg. Chem., 1972, 11, 2285. 8 D. Coucouvanis, S. J. Lippard, and J. A. Zubieta, Inorg. Chem., 1970, 9, 2775. Q L. H. Pignolet, Inorg. Chem., 1974, 13, 2051.",
year = "1975",
doi = "10.1039/C39750000049",
language = "English (US)",
pages = "49--50",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "2",
}